50900
Fluka
(−)-Guaiol
purum, ≥98.0% (sum of enantiomers, HPLC)
| Synonym: | (3R,6S,10S)-6,10,α,α-Tetramethylbicyclo[5.3.0]dec-1(7)-ene-3-methanol |
| CAS Number: | 489-86-1 |
| Linear Formula: | C15H26O |
| Molecular Weight: | 222.37 |
| Beilstein Registry Number: | 2047993 |
| EC Number: | 207-702-8 |
| MDL number: | MFCD00043336 |
| PubChem Substance ID: | 24873449 |
Description
| Other Notes | Sesquiterpene alcohol found in the oil of Guaiac wood and the wood oil of other trees1,2; Dehydration with benzoyl chloride and oxidation with tert-butyl chromate leads to a dienone3 |
Properties
| grade | purum |
| assay | ≥98.0% (sum of enantiomers, HPLC) |
| optical activity | [α]20/D −28±2°, c = 4% in ethanol |
| mp | 91-93 °C(lit.) |
| 91-93 °C | |
| storage temp. | 2-8°C |
Safety
| Personal Protective Equipment | Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter |
| Safety Statements | 22-24/25 |
| WGK Germany | 3 |
References
| Cited Reference | 1. O. Wallach Justus Liebigs Ann. Chem. 279, 395, (1894) |
| 2. P.A. Plattner, G. Magyar Helv. Chim. Acta 25, 581, (1942) | |
| 3. S.K. Paknikar, V.P. Kamat Indian J. Chem. B 22B, 1060, (1983) | |
| Merck | Merck 13,4572 |
| Beilstein | Beil. 6,III,412 |
| reference | FT-IR 2 (1), 239:A |
